CHEM 240: Introduction to
Bioanalytical Chemistry

J. D. Cronk
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Lecture 1. Introduction

Wednesday 12 January 2005

Introduction. Units of measurement, conversion. Definitions of concentration.

Reading: Harris - Ch.1, p.13-25. Problems: Ch.1 - 12, 14, 17, 18, 19, 21, 22.

 

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Lecture 1 Summary

We briefly consider the various units of measurement, terminology and conversions, and the importance of dimensional analysis, and solution chemistry. To understand solution chemistry, we need to be familiar with the definitions of solute, solvent, and solution. Solutes may be strong or weak electrolytes. There are several definitions of concentration, all of which apply to solution chemistry. Molar concentration, or molarity, is defined in terms of moles solute per liter solution. Concentrations may also be expressed as mass of solute over volume solution. units (e.g. grams per liter). Molality is defined as mole solute per 1000 g (1 kg) of solvent. The text discusses preparation of solutions. Analytical chemists make use of percentage or fractional composition of solutions or mixtures. The units parts per million (ppm) and parts per billion (ppb) were defined and discussed.

Example: In Problem 1-20, we convert volume and density to mass in g, and the latter to moles of a solute (methanol) in order to calculate the molar concentration of the solution. Note that in this example, the solute and solvent are both liquids. Also, you should "ask yourself" in performing this calculation, what is the proper number of significant figures in the answer?
 
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